Pressure accumulator

ABSTRACT

The invention relates to a pressure accumulator comprising a membrane ( 4 ) which forms a movable separating element between media spaces ( 6, 8 ) and which is made of contiguous layers ( 16, 18, 20, 22, 24, 26 ) of different materials, said pressure accumulator being characterized in that at least one layer of a basic structure ( 16, 20 ) having filaments and provided with a gas-tight impregnation ( 24 ) is disposed between layers ( 18 ) made of an elastomer.

The invention relates to a pressure accumulator comprising a membrane which forms a moveable separating element between media spaces, and which is made of contiguous layers of different materials.

Pressure accumulators of this kind, which are so-called membrane accumulators, are prior art. Such pressure accumulators may be used in hydraulic systems as shock absorbers or pulsation dampers to dampen pressure shocks in a circuit. Moreover, they may also be used as an energy source for a pump-less emergency circuit, and are also suitable, for example, as hydraulic compression springs and such like.

When using such pressure accumulators with a process gas, such as air or preferably nitrogen, the disadvantage is that the diaphragm becomes permeable to the enclosed gas depending on the chemical composition of the elastomer and its service life. The nitrogen or the air first dissolve in the elastomer and subsequently diffuse into the environment through evaporation. Thus the amount of gas present in the storage system diminishes and the operational reliability declines rapidly. This renders the storage system unserviceable beyond reuse and it must be discarded.

To increase the permeation resistance of an elastic, largely gastight synthetic membrane it is known from the prior art to provide a multilayered composition of the membrane, where a layer from a cross-linked polysiloxane is applied through scraping on, spraying on, pouring on or brushing on (cf. DE 42 31 927 C2).

In another solution known from the prior art (see DE 44 05 009 A1), a first and a second synthetic membrane are provided to create a multilayered membrane unit, in which the first synthetic membrane consists of an elastomer and the second synthetic membrane is a polyester film.

Based upon said prior art it is the object of the invention to provide a pressure accumulator, the membrane of which is characterized by a further improved permeation resistance that remains intact for long operating periods.

This object is met, according to the invention, by a pressure accumulator that exhibits all of the characteristics of claim 1. In accordance with this the invention is characterized in that the multilayered membrane unit is provided with at least one layer of a base structure that comprises filaments and which has a gastight impregnation, and where said base structure is disposed between layers of an elastomer. When using a composition in a multilayered membrane unit that uses filaments as a constituent, the danger that layers, which have been applied to a substrate to increase gastightness, will lift off or flake off, is avoided. Due to the kneading action that the membrane is subjected to during operation, the prior art is prone to cracking in operation, which may lead to lifting off or flaking off. In contrast, with the gastight impregnation of a base structure that comprises filaments, according to the invention, a deep, permanent bond is created while maintaining a high permeation resistance through the penetration of the impregnation and the surrounding of the filaments on the base structure.

The base structure may advantageously be formed from a synthetic textile, a knitted fabric or non-woven, but a synthetic textile made from polyamide (PA 6.6) is preferred.

In an advantageous embodiment the membrane may comprise, in succession, a layer of nitrile rubber (NBR), an impregnated base structure, a further layer of nitrile rubber (NBR), a second impregnated base structure, and a third layer of nitrile rubber (NBR). When providing two gastight impregnated base structures as part of the membrane unit, a particularly high permeation coefficient can be achieved.

Providing the impregnation to both sides of the respective base structure by applying a layer of polyvinyl acetate (PVAc) can be of particular advantage.

Moreover, a barrier layer of ethylene vinyl alcohol copolymer (EVOH) may be provided with particular advantage between the respective impregnated base structure and a layer of nitrile rubber (NBR).

In a particularly advantageous exemplary embodiment the membrane comprises, in succession, a barrier layer of nitrile rubber (NBR) with adhesive coating, a layer of ethylene vinyl alcohol copolymer (EVOH), an impregnated layer of polyvinyl acetate (PVAc), a base structure, an impregnated layer of polyvinyl acetate (PVAc), a barrier layer of ethylene vinyl alcohol copolymer (EVOH), an adhesive coating, a barrier layer of ethylene vinyl alcohol copolymer (EVOH), an impregnated layer of polyvinyl acetate (PVAc), a second base structure, an impregnated layer of polyvinyl acetate (PVAc), a barrier layer of ethylene vinyl alcohol copolymer (EVCH) [sic] as well as an adhesive coating on a layer of nitrile rubber (NBR).

The invention is now explained in greater detail by way of the drawing. Shown are in:

FIG. 1 a schematic longitudinal section of an exemplary embodiment of the pressure accumulator according to the invention;

FIG. 1a a highly enlarged, schematic representation (not to scale) of the section of the membrane of the exemplary embodiment marked in FIG. 1, and

FIG. 2 a schematic representation according to FIG. 1a of a section of the membrane of a modified exemplary embodiment.

FIG. 1 depicts a pressure accumulator according to the invention with an accumulator housing 2 featuring a welded design, in which a multilayered membrane 4, acting as a moveable separator, separates a fluid side 6 from a gas side 8. Said gas side 8 may be filled with a process gas, such as nitrogen, via a fill socket 10. The fluid side 6 is provided with a fluid connector 12, serving as a connection to a not-depicted hydraulic system. In the central region of the membrane 4, on the side that faces the fluid connector 12, a valve disk 14 is disposed, which closes the fluid connector 12 when the fluid side 6 is fully drained and the membrane 4 is extended correspondingly. FIG. 1 depicts the membrane 4 in a position which it assumes when the accumulator is fully drained and depressurized.

FIG. 1a provides a schematic representation of the layer structure of an exemplary embodiment of membrane 4. In the depicted example a gastight impregnated base structure 16 with filaments is disposed between two layers of an elastomer, such as NBR. A coating of polyvinyl acetate has been applied to both sides of the base structure 16 to provide a gastight impregnation. This priming coat is not depicted in FIG. 1 a. The base structure 16 itself is made from a polyamide PA 6.6 synthetic fabric. The membrane 4 of the example shown in FIG. 1a features a second gastight impregnated base structure 20 which, like the first base structure 16, is disposed between layers of elastomer 18. Analogous to the base structure 16, the second base structure 20 is also made from a polyvinyl acetate PA 6.6 synthetic fabric, and an impregnating priming coat of polyvinyl acetate is also applied to both sides. The practical implementation of the membrane 4, which is formed of the layers stated above, has an overall thickness of 0.6 mm.

In the exemplary embodiment depicted in FIG. 2, the membrane 4 is provided, in addition to the layers provided in the first example, on every side of the impregnating priming coat of the first and second base structure 16 and 20 each with a barrier layer 22 made of ethylene vinyl alcohol copolymer (EVOH), which is contiguous to the impregnating priming coat 24 on both sides of the first and second base structure 16, 20, as shown in FIG. 2. An adhesive coating 26 is disposed between the two outer layers of the elastomer 18 and the subsequent barrier layer 22, as well as between the adjacent barrier layers 22 of the first and second base structure 16, 20.

Analogous to the first described example, the membrane 4 may also be produced to have an overall thickness of 0.6 mm despite the greater number of layers as per the example of FIG. 2. For example, the thickness of the outer layers of elastomer 18 and adhesive coating 26 may each be 0.15 mm. The thicknesses of the first and second base structure 16, 20 including priming coats 24 and barrier layers 22 may each be 0.13 mm and the central adhesive coating 26 may have a layer thickness of 0.04 mm. As a result of two pairs of additional barrier layers 22 of ethylene vinyl alcohol copolymer EVOH, which are disposed on both sides of and adjacent to the first and second base structure 16, 20, the highest level of gastightness of the membrane 4 can be achieved.

The gastight impregnation 24 is applied in-situ into the base structure, and the otherwise commonly applied adhesive and connecting layers, particularly in form of adhesive coatings, can be omitted completely in this section. Moreover, the impregnation applied to the base structure also stiffens the fabric layer and is thus reinforcing it. 

1. Pressure accumulator, comprising a membrane (4) which forms a moveable separating element between media spaces (6, 8), and which is made of contiguous layers (16, 18, 20, 22, 24, 26) of different materials, characterized in that at least one layer of a base structure (16, 20) is provided that comprises filaments and which has a gastight impregnation (24), and where said base structure is disposed between layers (18) of an elastomer.
 2. Pressure accumulator according to claim 1, characterized in that the respective base structure (16, 20) that comprises filaments is formed from a textile, a knitted fabric or a non-woven.
 3. Pressure accumulator according to claim 1, characterized in that more than one layer of filament-containing, impregnated base structure (16, 20) is provided.
 4. Pressure accumulator according to claim 1, characterized in that between the base structures (16, 20) at least one further layer is provided, of which at least one layer consists of an elastomer (18, 26).
 5. Pressure accumulator according to claim 1, characterized in that the impregnated base structure (16, 20) comprises a synthetic fabric, preferably made of polyamide (PA 6.6).
 6. Pressure accumulator according to claim 1, characterized in that the membrane comprises, in succession, a layer (18) of nitrile rubber (NBR), an impregnated base structure (16), a further layer (18) of nitrile rubber (NBR), a second impregnated base structure (20), and a third layer (18) of nitrile rubber (NBR).
 7. Pressure accumulator according to claim 1, characterized in that for forming the impregnation on both sides of the respective base structure (16, 20) a layer (24) of polyvinyl acetate (PVAc) is provided.
 8. Pressure accumulator according to claim 1, characterized in that a barrier layer (22) made from ethylene vinyl alcohol copolymer (EVOH) is provided between the respective impregnated base structure (16, 20) and a layer (18, 26) of nitrile rubber (NBR).
 9. Pressure accumulator according to claim 1, characterized in that the membrane comprises, in succession, a layer (18) of nitrile rubber (NBR) with adhesive coating (26), a barrier layer (22) of ethylene vinyl alcohol copolymer (EVOH), an impregnated layer (24) of polyvinyl acetate (PVAc), a base structure (16), an impregnated layer (24) of polyvinyl acetate (PVAc), a barrier layer (22) of ethylene vinyl alcohol copolymer (EVOH), an adhesive coating (26), a barrier layer (22) of ethylene vinyl alcohol copolymer (EVOH), an impregnated layer (24) of polyvinyl acetate (PVAc), a second base structure (20), an impregnated layer (24) of polyvinyl acetate (PVAc), a barrier layer (22) of ethylene vinyl alcohol copolymer (EVOH) as well as an adhesive coating (26) on a layer (18) of nitrile rubber (NBR). 